Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. What causes stress corrosion cracking in pipelines. Whether the threat is classic scc or nearneutral ph scc, a comprehensive program is required including design, construction, monitoring, mitigation, assessment and remediation. Pr306163607r01 near neutral ph stress corrosion cracking, influence of environmental parameters authors elisabeth fleury corrosion project manager grtgaz research and innovation center for energy. This mechanism is characterized by corrosion in the microscopic granular composition of a metals surface. Coating type and condition have the strongest effect on scc initiation and growth. Scc occurs when the tensile stress and a specific environment are able to cause failure by their combined action, but are insufficient to cause failure by either one acting alone. Stress corrosion crack growth rates in unsensitized stainless steels and nickel alloys in hightemperature pure bwr and bli pwr primary water were evaluated. Stress corrosion cracking, stress, fracture materials, storage, acceptance criteria, bearings, cooling, cracking.
Managaing nearneutral ph scc 4 of 158 3rd edition, may 2015 term definition collapse limit plastic collapse limit the maximum stress, strain or load which may be applied prior to onset of plastic collapse. The risk factors are still not completely understood, and the tools. Although it has traditionally been termed stress corrosion cracking, crack growth has never been observed under a static loading condition. As such, the newly discovered form of scc is equally referred to as transgranular scc or nearneutral ph scc.
Du and coworkers investigated the influence of ac on the stress corrosion cracking scc behavior of pipeline steels in high ph and nearneutral ph solutions. Effects of sulfur compounds on the pitting behavior of type. Stress corrosion cracking scc of buried pipelines has been a recognized threat since 1965. These growth rates show a continuum response across stainless steels and nickel alloys, corrosion potential. Two patches of nearneutralph stress corrosion cracks scc, as developed on a pipeline steel during service, have been characterized. Stress corrosion cracking of pipeline steels in nearneutral. Pdf environmentally induced cracking of api grade steel. Stress corrosion cracking direct assessment sccda what is stress corrosion cracking. Stress corrosion cracking of pipeline steels in nearneutral ph. Pr306163607r01 near neutral ph stress corrosion cracking.
Effects of sulfur compounds on the pitting behavior of. Characteristics and historical information on both forms of cracking are discussed. Stress corrosion cracking is a form of localised failure which is more severe under the combined action of stress and corrosion than would be expected from the sum of the individual effects acting alone. This report includes a compilation of results obtained through a series of white papers developed as part of a gas transmission company jip. The standard applies wherea the temperatures of the fluid are not more than 200c nor less than 30c. Stress corrosion cracking scc in nearneutral ph environment remains a major concern for high pressure pipelines transporting oil and gas. No matter how well these pipelines are designed, constructed and protected, once in place they are subjected to environmental abuse, external damage, coating disbondments, inherent mill. The rupture had originated at stress corrosion cracks on the outside surface of the pipe, consistent with nearneutral ph stress corrosion cracking. Chen w 2016 an overview of near neutral ph stress corrosion cracking in pipelines and mitigation strategies for its initiation and growth. Also, the environment at the bottom of a pit will become more acidic. This information is then used to support proposed mechanisms for crack initiation and growth.
The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. We are now pleased to make our report to the board pursuant to section 15 of the. Canadian energy pipeline association cepa 2015 recommended practices for managing near neutral ph stress corrosion cracking 3rd edition, 158. The stress corrosion cracking of the steel was dominated by an anodic dissolution mechanism, while the effect of hydrogen was negligible. An overview of nearneutral ph stress corrosion cracking in. Those that do will usually be those that do not promote widespread corrosion in the sense of. The deposit of corrosion products at the crack tip could protect somewhat from further corrosion. The scope of the journal includes the latest developments in areas of corrosion.
This is the only mention of nearneutral scc in asme b31. Initiating nearneutral ph scc in the laboratory under stressing conditions that are representative of those on an operating gas pipeline has proven very difficult. Software package for pipe axial flow failure criterion to determine the failure conditions associated. Initiating near neutral ph scc in the laboratory under stressing conditions that are representative of those on an operating gas pipeline has proven very difficult. In the case of near neutralph scc, the cracking environment. Stress corrosion cracking colony near the fracture surface from a ruptured section of pipe. Internal stresscorrosion cracking by aqueous solutions of co. No matter how well these pipelines are designed, constructed and protected, once in place they are subjected to environmental abuse, external damage, coating disbondments, inherent mill defects, soil movementsinstability and third party damage. The steel samples were immersed in an anaerobic dilute, near neutral solution with an open circuit potential for various times under stress.
Stress corrosion crack scc growth mechanisms in pipeline steels exposed to near neutral ph environments are not well understood, although cracking is generally thought to result from some. Most leaks or ruptures due to stress corrosion cracking scc originate at clusters of cracks that are oriented in the longitudinal, or axial, direction of the pipe. Combined effect of alternating current interference and. We have completed the public inquiry into stress corrosion cracking on canadian oil and gas pipelines in accordance with the boards terms of reference of 6 september 1995. The criteria for the quantitative assessment of the influence of mce and cme.
In the liquid nprm, phmsa proposed to add a new definition of significant stress corrosion cracking. Environmentally induced cracking of api grade steel in near. King, development of guidelines for identification of scc sites and estimation of. Stress corrosion cracking international institute of. They found that ac interference changed the high ph scc mode from intergranular to transgranular 15 and the nearneutral ph scc susceptibility was enhanced by ac current 16.
It is important to realize that not all corrosive environments promote the formation of stress corrosion cracks. The source of the co 2 is typically the decay of organic matter and geochemical reactions in the soil. The cracks had grown and coalesced over time, reducing the loadbearing capacity of the pipeline steel at normal operating pressures. Andresen, in stress corrosion cracking of nickel based alloys in watercooled nuclear reactors, 2016. The severity of four different soil environments toward the development of near neutral ph stress corrosion cracking scc of pipeline steel was evaluated using slow strainrate testing ssrt. Development of guidelines and algorithms for prioritizing pipeline segments and hcas for scc assessment, and for selecting excavation sites most likely to show evidence of scc. Industry guidelines have been proposed elsewhere to identify where high ph scc and nearneutral ph scc are most likely. Although criteria and mitigation plans for nearneutral ph 68 scc is not addressed in this standard, nace international nace is currently developing a standard on direct assessment of. Although criteria and mitigation plans for near neutral ph 68 scc are not addressed in this standard, nace international nace is currently developing a standard on direct assessment of stress corrosion cracking. As such, the newly discovered form of scc is equally referred to as transgranular scc or near neutral ph scc.
Characteristics of nearneutralph stress corrosion cracks in an x. The growth rates of transgranular stress corrosion cracks have been modeled and determined by conducting laboratory tests under similar conditions to those recorded in practice. Stress corrosion cracking of pipeline steels in near. For near neutral ph scc, cracking is most common under tape coated and asphalt coated lines.
These soils were collected from pipeline sites where nearneutral ph scc has been observed. This paper provides an overview of mechanisms for highph and nearneutral ph stress corrosion cracking of underground pipelines. They found that ac interference changed the high ph scc mode from intergranular to transgranular 15 and the near neutral ph scc susceptibility was enhanced by ac current 16. Du and coworkers investigated the influence of ac on the stress corrosion cracking scc behavior of pipeline steels in high ph and near neutral ph solutions. For scc to occur, carbon dioxide, carbon monoxide, and water must be simultaneously present. Stress corrosion cracking an overview sciencedirect topics. Stress corrosion cracking scc is a fracture process that involves the combined and simultaneous action of a tensile stress and a corrosive environment. The new definition provides criteria for determining when a probable crack defect in a pipeline segment must be excavated and repaired. This mode of failure has been under investigation since 1965, when highph scc was first discovered, and near neutral ph scc. Colony an area of stress corrosion cracks occurring in groups of a few to thousands of cracks within a relatively. They result from a series of findings of an extensive national energy board board public inquiry into the problem of nearneutral ph stress corrosion cracking scc. The influence of these processes on the mechanism and kinetics of corrosion cracking of pipe steels in nearneutral aqueous solutions is discussed. Environmental aspects of nearneutral ph stress corrosion.
Mar 04, 2020 stress corrosion cracking colony near the fracture surface from a ruptured section of pipe. Stress corrosion cracking in pipeline steels scientific. Chlorideinduced stress corrosion crack growth under dry. It has been found that low ph scc occurs in environments with a low concentration of. The specificity of environments that will promote stress corrosion cracking is significant. Stress corrosion cracking scc of pipeline steels in nearneutral ph environments has remained a significant integrity risk for oil and gas pipelines. Stress corrosion cracking of pipeline steel in nearneutral. In the introduction to stress corrosion cracking on canadian oil and gas pipelines the neb notes. Over the past several years, investigations have been carried out into the rate of crack growth in pipeline steels in simulated, nearneutral ph, groundwater environment ns4 solution.
It has been found that low ph scc occurs in environments with a low concentration of carbonic acid and bicarbonate ions with the presence of other species, including chloride, sulfate and nitrate ions. Stress corrosion crack growth rates in unsensitized stainless steels and nickel alloys in hightemperature pure. Stress corrosion cracking scc of pipeline steels in near neutral ph environments. As defined in the nace standard rp02042004, stress corrosion cracking scc is the cracking of material produced by the combined action of corrosion and tensile stress residual or applied. Prior to the discovery of this new form of cracking, scc was thought to be a relatively wellunderstood, intergranular. Precracked specimens were subject to constant amplitude loading under various frequencies, maximum loads and rratios minimummaximum load. Twentyseven recommendations to promote public safety on canadas buried oil and gas pipelines are presented in this report. Pipeline transportation safety investigation p18h0088. Most leaks or ruptures due to stresscorrosion cracking scc originate at clusters of cracks that are oriented in the longitudinal, or axial, direction of the pipe. An overview of nearneutral ph stress corrosion cracking. This mode of failure has been under investigation since 1965, when highph scc was first discovered, and nearneutralph scc sometime called lowph scc has been studied intensely since it was discovered in 1986.
The influence of these processes on the mechanism and kinetics of corrosion cracking of pipe steels in near neutral aqueous solutions is discussed. Stress corrosion cracking the international institute of. Our awareness of scc on the canadian pipelines we regulate began in 1985. Asme stppt0112008 integrity management of stress corrosion cracking in gas pipeline high consequence areas stppt011 2008 this report includes a compilation of results obtained through a series of white papers developed as part of a gas transmission company jip addressing specific issues related to scc in gas pipeline hcas. Stress corrosion cracking of pipeline steels in nearneutral ph solutions. Pipeline stress corrosion cracking over 98% of pipelines are buried. The severity of four different soil environments toward the development of nearneutral ph stress corrosion cracking scc of pipeline steel was evaluated using slow strainrate testing ssrt. Battelle columbus laboratories study of stresscorrosion cracking scc of linepipe steel in aqueous solutions of co and cosub 2 revealed that pipeline steels are susceptible to scc at partial pressures of cosub 2 and co as low as 1 psi 6. Scc direct assessment methodology is a procedure that can identify areas where either nearneutralph scc or highph scc can occur on external pipe surfaces. Development of guidelines for identification of scc sites. What strategies are available for addressing stress corrosion cracking.
Bala srinivasan,helmholtzzentrum geesthacht, germanyand v. Integrity management of stress corrosion cracking in gas pipeline high consequence areas stppt011 2008 the american society of mechanical engineers on. Fullscale stress corrosion crack growth testing of an x70 spiral. Significant stress corrosion crackingmeans a stress corrosion cracking scc. Stress corrosion, also known as stress corrosion cracking, is a type of corrosion that occurs due to the simultaneous action of a corrodent and a sustained tensile stress. Cepa recommended practices for managing near neutral ph. Stress corrosion crack scc growth mechanisms in pipeline steels exposed to nearneutral ph environments are not well understood, although cracking is generally thought to result from some. Mechanical factors affecting stress corrosion crack growth. These soils were collected from pipeline sites where near neutral ph scc has been observed. Near neutral type scc similarly would require an inspection and alternative mitigation plan. Crack growth rate testing with instrumented boltload compact tension specimens under chlorideinduced stress corrosion cracking conditions in spent nuclear fuel canisters. Stress corrosion cracking industrial metallurgists. Although criteria and mitigation plans for nearneutral ph 68 scc are not addressed in this standard, nace international nace is currently developing a standard on direct assessment of. Additional guidance for management of the integrity of natural gas and liquid petroleum pipelines subject to nearneutralph scc is provided in the cepa stress corrosion cracking recommended practices.
Pdf stress corrosion cracking of pipeline steel in near. Battelle columbus laboratories study of stress corrosion cracking scc of linepipe steel in aqueous solutions of co and cosub 2 revealed that pipeline steels are susceptible to scc at partial pressures of cosub 2 and co as low as 1 psi 6. Cepa recommended practices for managaing nearneutral ph scc 1 of 158 3rd edition, may 2015 executive summary this 3rd stedition of the cepa recommended practices for stress corrosion cracking builds on the 1 and 2nd editions published in 1999 and 2007, respectively. Environmentally induced cracking of api grade steel in nearneutral ph soil article pdf available in journal of the brazilian society of mechanical sciences and engineering 312 june 2009. The applied load stress increased the corrosion rate at the crack tip, contributing to crack propagation. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Managaing near neutral ph scc 3rd edition, may 2015 contents executive summary 1 glossary of terms 3 1. Integrity management of stress corrosion cracking in gas. Nearneutral ph stress corrosion cracking nonclassic type a nearneutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. Near neutral ph stress corrosion cracking nonclassic type a near neutral ph scc environment appears to be a dilute groundwater containing dissolved co 2. These recommended practices represent an overview of the methods used by cepa member companies to. Scc in pipelines is a type of environmentally assisted cracking eac. Criteria for susceptibility to circumferential scc prci.